In their new adventure, Yuuna and Stitch move from their small island Izayoi to the Okinawa main island where Yuuna is supposed to visit a school. A new cast of friends awaits them there as well as a new crisis approaching from space. 
(Source: AniDB)

The second season of Stitch!, episode numbers continue from 27.

An exclusive episode showing the guest character, Kijimunaa's sister, who looks like Kijimunaa and is pink.
 
(Source: Wikipedia)

Ace appears to save the day and Stitch decides to help him.

To confront a planetary war at the sand planet of Katuuna, Stitch must leave Yuuna and Earth behind.

In the story, a mysterious giant tank rocket begins stealing resources from various planets. On Earth, Yuuna and Boogoo get involved in the incident and disappear. In order to save Yuuna, Stitch teams up with Tiira. 
 
(Source: Anime News Network)

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