Serizawa is the Lead Commander (筆頭局長) and the highest authority in the Shinsengumi. Although he has a sharp mind, he's quick-tempered, arrogant, and self-centered.  His outrageous behavior is the reason why Shinsengumi became notorious in Kyoto.  He looks down on Kondou and Hijikata.  Source: http://tokio-fujita.livejournal.com/1142.html

The year is 1863 and as Japan's long festering wounds of political discord erupt into violent waves of street clashes and murder, the Tokugawa Shogunate sends a new force of masterless samurai called the Roshigumi to the aid of the Aizu forces in Kyoto. However the new "police" are anything but a cohesive force and assassination has already split them into two opposing factions. The stronger is led by the brutal Serizawa Kamo and the lesser by the more honorable but less assertive Isami Kondo. It is into this pack of wolves that Ryunosuke Ibuki is dragged by the rabid Serizawa. Forced to be a virtual slave by blood debt, he hates the samurai and everything they stand for. But as he sees how the other half of the samurai live, he begins to believe that there may still be a chance, for both himself and Japan, if only Kondo will step up and take down the mad dog Serizawa! <br><br>
(Source: Sentai Filmworks) 

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Kamo Serizawa